Insensitivity of trapping at surfaces to molecular vibration

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Insensitivity of trapping at surfaces to molecular vibration

We have measured the trapping probability of NO(v = 0 and v = 2) on Au(1 1 1) as a function of translational energy of incidence. The range of translational and vibrational energies probed is comparable, yet the influence of the two types of motion is very different; 0.46 eV of translational energy is sufficient to completely suppress trapping, but the 0.46 eV of vibrational energy in NO(v = 2)...

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ژورنال

عنوان ژورنال: Chemical Physics Letters

سال: 2005

ISSN: 0009-2614

DOI: 10.1016/j.cplett.2005.06.031