Insensitivity of trapping at surfaces to molecular vibration
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Insensitivity of trapping at surfaces to molecular vibration
We have measured the trapping probability of NO(v = 0 and v = 2) on Au(1 1 1) as a function of translational energy of incidence. The range of translational and vibrational energies probed is comparable, yet the influence of the two types of motion is very different; 0.46 eV of translational energy is sufficient to completely suppress trapping, but the 0.46 eV of vibrational energy in NO(v = 2)...
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ژورنال
عنوان ژورنال: Chemical Physics Letters
سال: 2005
ISSN: 0009-2614
DOI: 10.1016/j.cplett.2005.06.031